Electrochemical cholesterylation of sugars with cholesteryl diphenylphosphate

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• 作者：Aneta M. Tomkiel^a ; Leszek Siergiejczyk^a ; Dorota Naró ; g^b ; Jolanta Płoszyńska^b ; Andrzej Sobkowiak^b ; Jacek W. Morzycki^a ; ^{morzycki@uwb.edu.pl}
• 关键词：Cholesterol ; Glycosylation ; Cholesterylation ; Cholesteryl diphenylphosphate ; Electrochemical oxidation
• 刊名：Steroids
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：117
• 期：Complete
• 页码：44-51
• 全文大小：880 K
• 卷排序：117

文摘

Electrochemical reactions of sugars with cholesteryl diphenylphosphate provide glycoconjugates. The cholesterylation reactions are completely stereoselective. Polyol reactions yield mono-, di-, tri-, or tetra-cholesterylated products.