Hydrodynamic Voltammetry at a Rocking Disc Electrode: Theory versus Experiment
详细信息 查看全文
- 作者：Sunyhik D. Ahna ; Karthik Somasundaramb ; H.Viet Nguyenc ; Erik Birgerssonb ; Jim Yang Leeb ; Xiangming Gaoc ; Adrian C. Fisherc ; Paul E. Fritha ; Frank Markena ; F.Marken@bath.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrodynamic modulation ; Plating ; Ionic liquid ; Convection ; Viscosity
- 刊名：Electrochimica Acta
- 出版年：2016
- 出版时间：10 January 2016
- 年：2016
- 卷：188
- 期：Complete
- 页码：837-844
- 全文大小：1299 K
文摘
- •
Experiments confirm well behaved limiting current with Levich-type equation quantitatively agreeing with uniformly planar diffusion.
- •
Theory developed to link the case of rotating disc voltammetry with the more complex rocking disc voltammetry.
- •
Close agreement of rocking disc voltammetry and rotating disc voltammetry when comparing the average angular movement for both methods.