3-dimensional carbon nanotube for Li-ion battery anode

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• 作者：Chiwon Kang ; Indranil Lahiri ; Rangasamy Baskaran ; Won-Gi Kim ; Yang-Kook Sun ; Wonbong Choi
• 关键词：Li-ion batteries ; Carbon nanotubes ; 3D Cu current collector ; Anode materials ; Amorphous Si ; a-Si/MWCNTs composite
• 刊名：Journal of Power Sources
• 出版年：2012
• 出版时间：1 December, 2012
• 年：2012
• 卷：219
• 期：Complete
• 页码：364-370
• 全文大小：1242 K

文摘

Carbon nanotubes, in different forms and architectures, have demonstrated good promise as electrode material for Li-ion batteries, owing to large surface area, shorter Li-conduction distance and high electrical conductivity. However, practical application of such Li-ion batteries demands higher volumetric capacity, which is otherwise low for most nanomaterials, used as electrodes. In order to address this urgent issue, we have developed a novel 3-dimensional (3D) anode, based on multiwall carbon nanotubes (MWCNTs), for Li-ion batteries. The unique 3D design of the electrode allowed much higher solid loading of active anode material, MWCNTs in this case and resulted in more amount of Li⁺ ion intake in comparison to those of conventional 2D Cu current collector. Though one such 3D anode was demonstrated to offer 50 % higher capacity, compared to its 2D counterpart, its ability to deliver much higher capacity, by geometrical modification, is presented. Furthermore, deposition of amorphous Si (a-Si) layer on the 3D electrode (a-Si/MWCNTs hybrid structure) offered enhancement in electrochemical response. Correlation between electrochemical performances and structural properties of the 3D anodes highlights the possible charge transfer mechanism.