- 作者：S. Lua ; C. Lia ; canli1983@gmail.com" class="auth_mail" title="E-mail the corresponding author ; H.H. Lia ; Y.F. Zhaoa ; Y.Y. Gonga ; L.Y. Niua ; X.J. Liua ; T. Wangb
- 关键词：Nonmetal doping ; Monolayer g&ndash ; C3N4 ; Chemical bond relaxation ; Electronic structure and photocatalytic ability
- 刊名：Applied Surface Science
- 出版年：2017
- 出版时间：15 January 2017
- 年：2017
- 卷：392
- 期：Complete
- 页码：966-974
- 全文大小：4460 K
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The electronic structures have been altered by the newly formed C
NM bonds and the relaxed chemical bonds around them.- •
The optical absorption edge (and intensity) in visible-light range red-shifts 10–75 nm (and increases about 14%–71%) except O– and S– doped specimens.
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The separation of the HOMO and LUMO of H–, B–, O–, S–, F– and As– doped specimens can effectively enhance the photocatalytic efficiency.The electronic structures have been altered by the newly formed C
NM bonds and the relaxed chemical bonds around them.- •
The optical absorption edge (and intensity) in visible-light range red-shifts 10–75 nm (and increases about 14%–71%) except O– and S– doped specimens.
- •
The separation of the HOMO and LUMO of H–, B–, O–, S–, F– and As– doped specimens can effectively enhance the photocatalytic efficiency.