A novel and simple electrochemical sensor for electrocatalytic reduction of nitrite and oxidation of phenylhydrazine based on poly (o-anisidine) film using ionic liquid carbon paste electrode

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• 作者：Reza Ojani ; ^{fer-o@umz.ac.ir} ; Jahan-Bakhsh Raoof ; Saeed Zamani
• 关键词：Poly (o- anisidine) ; Nitrite ; Phenylhydrazine ; Modified electrode ; Sensor
• 刊名：Applied Surface Science
• 出版年：2013
• 出版时间：15 April, 2013
• 年：2013
• 卷：271
• 期：Complete
• 页码：98-104
• 全文大小：873 K

文摘

In this study, nitrite electroreduction and phenylhydrazine electrooxidation were investigated on poly(o-anisidine) formed by cyclic voltammetry at the surface of ionic liquid carbon paste electrode. The films were characterized by cyclic voltammetry and scanning electron microscopy (SEM) and were contrasted with poly(o-anisidine) prepared under identical conditions in the absence of ionic liquid in carbon paste electrode. This carbon paste modified electrode exhibits a good electrocatalytic capability (via an EC¡¯ mechanism) for both electrooxidation and electroreduction of some important molecules. The obtained results showed that the catalytic oxidation peak currents of phenylhydrazine and catalytic reduction peak currents of nitrite at the surface of this simple (unfunctionalized) polymeric electrode were linearly dependent on their concentrations. Electrode was successfully applied for determination of nitrite and phenylhydrazine in real samples.