Characterization of biofuel refinery byproduct via selective electrospray ionization tandem mass spectrometry
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- 作者：Kelsey S. Boesa ; Robert H. Narronb ; Yufei Chena ; Sunkyu Parkb ; Nelson R. Vinuezaa ; nrvinuez@ncsu.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Biomass pretreatment ; Tandem mass spectrometry ; Lignin ; Oligosaccharides ; Time-of-flight ; Electrospray ionization
- 刊名：Fuel
- 出版年：2017
- 出版时间：15 January 2017
- 年：2017
- 卷：188
- 期：Complete
- 页码：190-196
- 全文大小：1015 K
文摘
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Electrospray provides soft ionization of autohydrolyzate from 100 to 3200 m/z.
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Ionization dopants allow discrete analysis of cellulose and lignin sans separation.
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Chloride attachment in electrospray ionization assists in ionizing hemicellulose.
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Deprotonation by hydroxide specifically enhances ionization of lignin derivatives.