Elevated CO2 stimulation of soil N2O emissions was observed under both wheat and tall fescue. The form of N inputs dominated elevated CO2 effect on soil N2O emissions. Elevated CO2 stimulation of N2O emission only occurred when NO3−-N was present as the primary N source. eCO2-inhibition of plant NO3−-N utilization and/or eCO2-enhancement of soil labile carbon enhanced N2O emissions.