Anticancer, antimicrobial, spectral, voltammetric and DFT studies with Cu(II) complexes of 2-hydroxy-5-methoxyacetophenone thiosemicarbazone and its N(4)- substituted derivatives

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• 作者：Ercan Tü ; rkkan^a ; Ulku Sayin^b ; ^c ; Nesibe Erbilen^d ; Suray Pehlivanoglu^e ; Gokce Erdogan^f ; Halil Ugur Tasdemir^a ; Ahmet Ozgur Saf^d ; Leyla Guler^g ; Emine Guler Akgemci^d ; ^{egakgemci@gmail.com}
• 关键词：Thiosemicarbazone ; Copper(II) complexes ; EPR ; FT-IR ; Cyclic voltammetry ; Antimicrobial and anticancer activity ; DFT
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：831
• 期：Complete
• 页码：23-35
• 全文大小：2268 K
• 卷排序：831

文摘

New copper complexes of thiosemicarbazone derivatives were synthesized. The complexes were characterized by DFT studies and UV–Vis, FT-IR, EPR spectral analysis, cyclic voltammetry measurements. The relationship between the structure, electronic structure, antibacterial and cytotoxic activity were discussed.