A bifunctional calixarene designed for immobilisation on a natural polymer and for metal complexation

详细信息    查看全文

• 作者：Engrand ; Philippe ; Regnouf-de-Vains ; Jean-Bernard
• 刊名：Tetrahedron Letters
• 出版年：2002
• 出版时间：December 2, 2002
• 年：2002
• 卷：43
• 期：4
• 页码：8863-8866
• 全文大小：208 K

文摘

The present work describes the multi-step synthesis of a new bifunctional calix[4]arene designed for grafting on natural polymeric materials, such as water-soluble dextrans, and for metal complexation. The podand was then anchored to the polymer by means of a cyanuric linker. The resulting material showed an interesting ability to complex copper(I), giving stable yellowish light orange solids and aqueous solutions.