Solvent dependent nuclearity of manganese complexes with a polydentate hydrazone-based ligand and thiocyanate anions

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• 作者：Ghodrat Mahmoudi^a ; ^{mahmoudi_ghodrat@yahoo.co.uk} ; Ennio Zangrando^b ; Werner Kaminsky^c ; Piotr Garczarek^d ; Antonio Frontera^e ; ^{toni.frontera@uib.es}
• 关键词：Manganese ; Complex nuclearity ; Crystal engineering ; Self-assembly ; Solvent effect
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P1
• 页码：204-212
• 全文大小：3089 K
• 卷排序：455

文摘

Synthesis and X-ray structure of three novel Mn(II)–2-benzoylpyridyl-(2-picolyl)-hydrazone complexes. Description of the crystal structures by Hirshfeld surface analysis. Analysis of the supramolecular interactions in the solid state by DFT calculations. Evaluation of the energy associated to CH⋯π interactions.