The Rényi entropies of the Dicke model are presented. This quantum-optical model describes a single-mode bosonic field interacting with an ensemble of N two-level atoms. There is a quantum phase transition in the N→∞ limit. It is shown that there is an abrupt change in the Rényi entropy of order β at the transition point. Around the critical value of the coupling strength λc the Rényi entropy is proportional to the logarithm of the characteristic length and diverges as lnλc−λ for any order β. The pseudocapacity defined here in analogy with the heat capacity exhibits the phase transition. The critical exponent for the Dicke model is found to be 1 for any value of the parameter β.