Revising the formulization of the Narayanaswamy equation using the Adam-Gibbs theory
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- 作者：Robert N. Phalena ; Kimberley Cousinsb ; Timothy Usherc ; Michelle Youngd ; Renwu Zhangb ; RZhang@csusb.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Tool&ndash ; Narayanaswamy&ndash ; Moynihan (TNM) equation ; Adam-Gibbs theory ; Vogel-Tammann-Fulcher (VTF) equation ; Fragility/fragilities
- 刊名：Journal of Non-Crystalline Solids
- 出版年：2016
- 出版时间：1 December 2016
- 年：2016
- 卷：453
- 期：Complete
- 页码：59-65
- 全文大小：440 K
文摘
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The new formulas of x and Δh* better correlate with experimental values, with less error.
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The new formula of x predicts experimental data with polystyrene, while the original predicts an opposite trend.
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A strong relationship, among a variety of materials, was established between the fragility coefficient m and new x.