Coordination polymer [Li₂Co₂(Piv)₆(μ-L)₂]_n

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• 作者：Mikhail Bykov ; Anna Emelina ; Mikhail Kiskin ; Aleksei Sidorov ; Grigory Aleks ; rov ; Artem Bogomyakov ; Zhanna Dobrokhotova ; Vladimir Novotortsev ; Igor Eremenko
• 关键词：Cobalt ; Lithium ; Heterometallic complex ; Coordination polymer ; Carboxylate ligands ; X-ray analysis ; Magnetic properties ; Thermal decomposition ; Heat capacity ; Phase transition
• 刊名：Polyhedron
• 出版年：2009
• 出版时间：3 November 2009
• 年：2009
• 卷：28
• 期：16
• 页码：3628-3634
• 全文大小：462 K

文摘

The solid-state thermolysis (420–450 °С) of the new heterometallic coordination polymer [Li₂Co₂(Piv)₆(μ-L)₂]_n (1, Piv is the anion of pivalic acid, L is 2-amino-5-methylpyridine) followed by annealing of the decomposition products at 500 °С was shown to afford LiCoO₂ in quantitative yield. Compound 1 was characterized by X-ray diffraction and magnetic measurements.