Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex

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• 作者：Yury V. Rakitin ; Vladimir M. Novotortsev ; Vladimir N. Ikorskii ; Igor L. Eremenko
• 刊名：Mendeleev Communications
• 出版年：2006
• 出版时间：2006
• 年：2006
• 卷：16
• 期：1
• 页码：23-24
• 全文大小：233 K

文摘

The magnetic properties of a Mn^II dimer L₂Mn₂(μ-OOCCMe₃)₄ (L = 2,6-diaminopyridine) can be correctly described with allowance for isotropic bilinear (−2J₁ = 16.5 cm⁻¹) and biquadratic (−2J₂ = 0.49 cm⁻¹) exchange, the latter crucially influencing the magnetic susceptibility in the whole temperature range.