Synthesis of the first water-soluble trimetallic nitride endohedral metallofullerols

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• 作者：Iezzi ; Erick B. ; Cromer ; Frank ; Stevenson ; Paige ; Dorn ; Harry C.
• 关键词：Water-soluble ; Metallofullerols ; TNT ; Metallofullerenes ; Contrasting agents
• 刊名：Synthetic Metals
• 出版年：2002
• 出版时间：May 10, 2002
• 年：2002
• 卷：128
• 期：3
• 页码：289-291
• 全文大小：99.0 K

文摘

Novel water-soluble trimetallic nitride endohedral metallofullerols, Scb>3b>N·Cb>80b>(OH)b>border=0 SRC=/images/glyphs/BQ1.GIF>10b>(O)b>border=0 SRC=/images/glyphs/BQ1.GIF>10b>, have been synthesized from polyanionic radical intermediates. These metallofullerols were characterized using a variety of methods, although small quantities of material hamper the ability to fully characterize. Metallofullerols containing paramagnetic metal atoms could one day be used as MRI contrasting agents.