Further discussions on the geometry and fast diffusion of AlCl₄ cluster intercalated in graphite

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• 作者：M.S. Wu ; B. Xu ; C.Y. Ouyang ; ^{cyouyang@jxnu.edu.cn} ; ^{cyouyang@hotmail.com}
• 关键词：Al ion battery ; AlCl4 cluster ; Planar geometry ; van der Waals interaction
• 刊名：Electrochimica Acta
• 出版年：2017
• 出版时间：1 January 2017
• 年：2017
• 卷：223
• 期：Complete
• 页码：137-139
• 全文大小：376 K
• 卷排序：223

文摘

Han et al. comment on our recent paper “Geometry and fast diffusion of AlCl4 cluster intercalated in graphite” [Electrochim. Acta. 195 (2016) 158–165] and question the planar geometry of the AlCl4 cluster and thus the fast diffusion of the AlCl4 cluster in graphite. In this reply, we demonstrate that the planar geometry is reasonable and the ultrafast diffusion of the AlCl4 cluster is in good agreements with the experiments by Lin et al. [Nature 520 (2015) 325–328]. The reasons on why the graphite foam is better in terms of the rate performance than the natural graphite are also discussed.