Selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural to 2,5-furandicarboxyaldehyde in aqueous suspension of g-C₃N₄

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• 作者：Igor Krivtsov^a ; ^b ; Elisa I. Garcí ; a-Ló ; pez^c ; ^{elisaisabel.garcialopez@unipa.it} ; Giuseppe Marcì ; ^c ; Leonardo Palmisano^c ; Zakariae Amghouz^d ; José ; R. Garcí ; a^a ; Salvador Ordó ; ñ ; ez^e ; Eva Dí ; az^e
• 关键词：Carbon nitride ; Exfoliation ; Partial photocatalytic oxidation ; 5-Hydroxymethyl-2-furfural ; 2 ; 5-Furandicarboxaldehyde
• 刊名：Applied Catalysis B: Environmental
• 出版年：2017
• 出版时间：5 May 2017
• 年：2017
• 卷：204
• 期：Complete
• 页码：430-439
• 全文大小：2844 K
• 卷排序：204

文摘

HMF was partially photo-oxidised to FDC in aqueous medium in the presence of g-C3N4. Thermal exfoliation of g-C3N4 enhanced both HMF conversion and selectivity to FDC. O2− was the main reactive species responsible for HMF oxidation to FDC. Exfoliated g-C3N4 showed better activity and selectivity to FDC under sunlight.