A series of uniaxial tension tests are performed for the gamma irradiated SRSF with γ-radiation dose from 0 to 600 kGy. The tensile modulus of SRSF increases with the increase of radiation dose, while the fracture strength and fracture strain generally decrease. The alternation of mechanical properties mainly comes from the evolution of polymer network. A constitutive relation of irradiated SRSF is proposed by incorporating the radiation induced polymer network evolution.