A novel europium (III) nitridoborate Eu3[B3N6]: Synthesis, crystal structure, magnetic properties, and Raman spectra
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- 作者：Umut Aydemira ; 1 ; umut.aydemir@northwestern.edu" class="auth_mail" title="E-mail the corresponding author ; Ilkin Kokala ; 2 ; Yurii Protsb ; Tobias Fö ; rsterb ; 3 ; Jö ; rg Sichelschmidtb ; Falko M. Schappacherc ; Rainer Pö ; ttgenc ; Alim Ormecib ; Mehmet Somera ; msomer@ku.edu.tr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Europium (III) nitridoborate ; Mö ; ssbauer spectroscopy ; Electron spin resonance ; Quantum chemical calculations ; Vibrational spectra
- 刊名：Journal of Solid State Chemistry
- 出版年：2016
- 出版时间：July 2016
- 年：2016
- 卷：239
- 期：Complete
- 页码：75-83
- 全文大小：2205 K
文摘
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A novel europium (III) nitridoborate, Eu3[B3N6], was successfully synthesized.
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The 3+ oxidation state of Eu was verified by Mössbauer and ESR spectroscopy.
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Quantum chemical calculations find six electrons in the 4f subshell (4f6).
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The vibrational spectra of the compound with [B3N6]9− moieties is reported.