Crystal structure, magnetic properties and Mössbauer studies of [Fe(qsal)₂][Ni(dmit)₂]

详细信息    查看全文

• 作者：Christophe Faulmann ; Sté ; phane Dorbes ; Sté ; phane Lampert ; Kane Jacob ; Bé ; né ; dicte Garreau de Bonneval ; Gá ; bor Molná ; r ; Azzedine Bousseksou ; José ; Antonio Real ; Lydie Valad
• 关键词：X-ray crystal structures ; Mossbauer spectroscopy ; Spin crossover ; Metal bisdithiolene complex ; Magnetic properties ; Pressure effects
• 刊名：Inorganica Chimica Acta
• 出版年：2007
• 出版时间：1 October 2007
• 年：2007
• 卷：360
• 期：13
• 页码：3870-3878
• 全文大小：997 K

文摘

A new compound of formula [Fe(qsal)₂][Ni(dmit)₂] (1) has been synthesised, structurally and magnetically characterised (qsalH = N-(8-quinolyl)salicylaldimine, dmit²⁻ = 1,3-dithiol-2-thione-4,5-dithiolato). Its structural features and its magnetic behaviour were compared with those of [Fe(qsal)₂]-based complexes, and more particularly [Fe(qsal)₂][Ni(dmit)₂] · 2CH₃CN.