Mesoporous LiFeBO3/C hollow spheres are prepared by a template method.
Two LFB/C electrodes with different carbon contents are prepared and tested.
Lithium-ion diffusion coef铿乧ient in LFB/C is calculated by EIS.
The LFB/C-1 electrode shows superior electrochemical performances.
The LFB/C-1 electrode demonstrates good structural stability upon storage.