Characterization of the interfaces between Au(hkl) single crystal basal plane electrodes and [Emmim][Tf2N] ionic liquid
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- 作者：Paula Sebastiá ; n ; Ví ; ctor Climent ; victor.climent@ua.es" class="auth_mail" title="E-mail the corresponding author ; Juan M. Feliu ; juan.feliu@ua.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Emmim][Tf2N ionic liquid ; Gold single crystal ; Potential of zero charge ; Phase transition ; Laser induced temperature jump ; Cyclic voltammetry
- 刊名：Electrochemistry Communications
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：62
- 期：Complete
- 页码：44-47
- 全文大小：627 K
文摘
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The interphase between Au(hkl) and the ionic liquid [Emmim][Tf2N] is investigated.
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The voltammetric profile contains sharp peaks corresponding to phase transitions.
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These sharp peaks are very sensitive to the crystallographic structure.
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Laser induce temperature jump is used to determine the potential of maximum entropy.