Preparation of nanosilica-immobilized antioxidant and the antioxidative behavior in low density polyethylene

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• 作者：Peng Liu ; Hanying Tang ; Ming Lu ; Chong Gao ; Feng Wang ; Yanfen Ding ; Shimin Zhang ; Mingshu Yang ; ^{yms@iccas.ac.cn}
• 关键词：Silica ; Antioxidant ; Low density polyethylene ; Thermal oxidative stability
• 刊名：Polymer Degradation and Stability
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：135
• 期：Complete
• 页码：1-7
• 全文大小：1397 K
• 卷排序：135

文摘

This article reports a study of the preparation of nanosilica-immobilized antioxidant (SiO2-APTMS-AO) and the thermal oxidative stability of low density polyethylene (LDPE) nanocomposites containing SiO2-APTMS-AO. SiO2-APTMS-AO was prepared based on the fumed nanosilica which was firstly modified with an aminosilane coupling agent and then reacted with 3,5-Di-tert-butyl-4-hydroxybenzoic acyl chloride. Infrared spectroscopy, X-ray photoelectron spectroscopy and thermogravimetric analysis measurements confirmed that the antioxidant group was chemically immobilized onto nanosilica. LDPE/silica nanocomposites were prepared by melt mixing and then pressed into different films. The thermal oxidative stability of the nanocomposites was evaluated by thermogravimetric analysis in air atmosphere, oxidation induction time (OIT) and long-term accelerated thermal aging. The results showed that the SiO2-APTMS-AO can significant improve the thermal oxidative stability of LDPE nanocomposite. Because SiO2-APTMS-AO is based on inorganic nano-filler, in comparison to organic antioxidants, it might have advantages in thermal stability and migration stability during processing and application.