A convenient phosphine-free palladium-catalyzed direct arylation of thiazole under mild aerobic conditions
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- 作者：Xiao-Xi He ; Yan-Fang Li ; Ju Huang ; xianghuangj@163.com" class="auth_mail" title="E-mail the corresponding author ; Dong-Sheng Shen ; Feng-Shou Liu ; fengshou2004@126.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Bulky aniline ; Palladium complex ; Thiazole ; Direct arylation ; Aerobic condition
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 February 2016
- 年：2016
- 卷：803
- 期：Complete
- 页码：58-66
- 全文大小：2135 K
文摘
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A series of bulky aniline palladium complexes were synthesized.
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The application of the direct arylation of thiazoles with aryl bromides was explored.
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The catalytic system showed high activity at a low palladium of 0.5–0.05 mol% under aerobic conditions.