Direct SN₁ reaction at oxidized PPF surfaces

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• 作者：Meritxell Corté ; s^a ; ¹ ; Hassiba Smida^a ; ¹ ; Cristelle Mé ; riadec^b ; Fré ; dé ; ric Barriè ; re^a ; ^{frederic.barriere@univ-rennes1.fr} ; Corinne Lagrost^a ; ^{corinne.lagrost@univ-rennes1.fr}
• 关键词：Surface functionalization ; PPF ; SN1 reaction ; Monolayer
• 刊名：Electrochemistry Communications
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：75
• 期：Complete
• 页码：48-51
• 全文大小：393 K
• 卷排序：75

文摘

PPF samples prepared under a non-reductive Ar atmosphere present –OH terminations. Electron transfer kinetics for ferricyanide and dopamine are retained or improved. A facile SN1 reaction between the oxygen-rich surface and ferrocenemethanol is achieved. This surface functionalization procedure yields a sub(monolayer) of ferrocenyl units.