N-Heterocyclic carbene adducts of cyclopalladated ferrocenylimines: Synthesis, characterization and catalytic activity for the Suzuki–Miyaura reaction
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- 作者：Jing-Ya Li ; A-Juan Yu ; Yang-Jie Wu ; Yu Zhu ; Chen-Xia Du ; Hua-Wei Yang
- 关键词：Cyclopalladated ferrocenylimines ; N-Heterocyclic carbene ; Adducts ; Crystal structures ; Suzuki– ; Miyaura coupling reaction ; Aryl bromides
- 刊名：Polyhedron
- 出版年：2007
- 出版时间：23 July 2007
- 年：2007
- 卷：26
- 期：12
- 页码：2629-2637
- 全文大小：422 K
文摘
A series of novel air-stable carbene adducts of cyclopalladated ferrocenylimines have been synthesized and characterized. The structures of these complexes were determined by single-crystal X-ray analysis. These adducts have been successfully applied to the Suzuki–Miyaura coupling reaction under aerobic conditions. Good to excellent yields were obtained in short reaction times with a lower loading of the catalyst.