Structure and decomposition of the silver formate Ag(HCO₂)

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• 作者：Anna N. Puzan ; ^{anna_puzan@mail.ru} ; Vyacheslav N. Baumer ; Pavel V. Mateychenko
• 关键词：Silver formate ; Crystal structure ; Ag&ndash ; Ag pairs ; Layered structure ; Decomposition ; Formation of metal phase
• 刊名：Journal of Solid State Chemistry
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：246
• 期：Complete
• 页码：264-268
• 全文大小：946 K
• 卷排序：246

文摘

Silver formate Ag(HCO2) was synthesized and characterized. Layered packing of Ag-Ag pairs in the structure was found. Decomposition of Ag(HCO2) and formation of metal phase were studied. Rietveld-refined micro-structural characteristics during decomposition reveal the space relationship between the matrix structure and forming Ag phase REPLACE with: Space relationship between the matrix structure and forming Ag phase.