Ion pairing, H-bonding, and π–π interactions in copper(II) complex-organo-networks derived from a proton-transfer compound of the 1,10-phenanthroline-2,9-dicarboxylic acid

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• 作者：Abolghasem Moghimi ; Robabeh Alizadeh ; Hossein Aghabozorg ; Abbas Shockravi ; M. Carla Aragoni ; Francesco Demartin ; Francesco Isaia ; Vito Lippolis ; Andrew Harrison ; A. Shokrollahi and Mojtaba Shamsipur
• 关键词：Copper ; 1 ; 10-Phenanthroline-2 ; 9-dicarboxylic acid ; 2 ; 6-Pyridinediamine ; Hydrogen bonds ; Ion pairs
• 刊名：Journal of Molecular Structure
• 出版年：2005
• 出版时间：2005
• 年：2005
• 卷：750
• 期：1-3
• 页码：166-173
• 全文大小：450 K

文摘

The one-pot reaction between the novel proton transfer compound (pydaH₂)²⁺(phendc)²⁻, LH₂, and Cu(II) afforded the compounds (pydaH)₂[Cu(phendc)₂]·10H₂O, 1, and (pydaH)₂[Cu(phendc)(phendcH)]₂·5H₂O, 2, where pyda=2,6-diaminopyridine, and phendcH₂