Synthesis and Diels-Alder Reactions of 3-methylene-2-ferrocenylmethylenequinuclidine

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• 作者：Garcí ; a ; Marcos Martí ; nez ; Pé ; rez ; Georgina Espinosa ; Ochoa ; Francisco Lara ; et. al.
• 刊名：Tetrahedron
• 出版年：1997
• 出版时间：September, 1997
• 年：1997
• 卷：53
• 期：37
• 页码：12369-12376
• 全文大小：396 K

文摘

The synthesis and chemical reactivity in Diels-Alder reactions of the title compound 6 is described. When 6 was reacted with N-phenylmaleimide, a 3:1 mixture of isomers exo 14a and endo 14b was found, while with triazolinedione 13, a novel ferrocenyl heterocycle 15 was formed. The structures for 14b and 15 were confirmed by X-ray diffraction analysis.