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Ru-catalyzed CH functionalization of phenylglycine derivatives: Synthesis of isoquinoline-1-carboxylates and isoindoline-1-carboxylates
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文摘
N-unprotected phenylglycine derivatives have been functionalized selectively. Functionalization is catalyzed by Ru(II) complexes through oxidative coupling. Isoquinoline-1-carboxylates are obtained by coupling with internal alkynes. Isoindoline-1-carboxylates are obtained by coupling with methylacrylates.

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