Direct allylation of benzyl alcohols, diarylmethanols, and triarylmethanols mediated by XtalFluor-E

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• 作者：Thomas Lebleu ; Jean-Franç ; ois Paquin ; ^{jean-francois.paquin@chm.ulaval.ca}
• 关键词：Benzyl alcohols ; Diarylmethanols ; Triarylmethanols ; Allylation ; Diethylaminodifluorosulfinium tetrafluoroborate
• 刊名：Tetrahedron Letters
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：58
• 期：5
• 页码：442-444
• 全文大小：648 K
• 卷排序：58

文摘

XtalFluor-E mediates the direct allylation of benzylic alcohols derivatives. Benzyl alcohols, diarymethanols, and triarylmethanols can be used as substrates. A wide range of allylated products can be obtained in moderate to excellent yield. For electron-poor benzyl alcohols, dibenzylethers are observed as major side products.