DBTTF derivative with bis(propylenedioxy) (BPDO) groups: Synthesis, electrochemical properties, conductivity, and crystal and band structures of salts
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- 作者：Tomoko Inayoshi ; inayoshi@chem.aoyama.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Masaki Sanada ; Shiro Matsumoto
- 关键词：TTF ; tetrathiafulvalene ; DBTTF ; dibenzo TTF ; PDO ; propylenedioxy ; BPDO-DBTTF ; bis(PDO)-DBTTF ; TMO-DBTTF ; tetramethoxy-DBTTF ; MDO ; methylenedioxy ; BMDO-DBTTF ; bis(MDO)-DBTTF ; EDO ; ethylenedioxy ; BEDO-DBTTF ; bis(EDO)-DBTTF ; BPDT-TTF ; bis(propylenedithio)-TTF ; TCNQ ; 7 ; 7 ; 8 ; 8-tetracyanoquinodimethane ; FTCNQ ; 2-fluoro-TCNQ ; F2TCNQ ; 2 ; 5-difluoro-TCNQ ; F4TCNQ ; 2 ; 3 ; 5 ; 6-tetrafluoro-TCNQ ; MeTCNQ ; 2-methyl-TCNQ ; Me2TCNQ ; 2 ; 5-dimethyl-TCNQ ; MeO)2TCNQ ; (dimethoxy-TCNQ ; TCNE ; tetracyanoethylene ; TNAP ; 11 ; 11 ; 12
- 刊名：Synthetic Metals
- 出版年：2016
- 出版时间：October 2016
- 年：2016
- 卷：220
- 期：Complete
- 页码：174-186
- 全文大小：4190 K
文摘
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Bis(propylenedioxy)-dibenzotetrathiafulvalene (BPDO-DBTTF) donor was synthesized.
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Electrochemical properties of BPDO-DBTTF were investigated by cyclic voltammetry.
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Some CT complexes and a radical salt had high conductivities and were semiconductors.
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X-ray crystal structures of Au(CN)4, GaCl4·PhCN, and SbF6·TCE radical salts were determined.
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Band structure of SbF6·TCE radical salt was calculated by the extended Hückel method.