Physicochemical and thermodynamic properties of imidazolium ionic liquids with nitrile and ether dual functional groups

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• 作者：Jaganathan Joshua Raj^a ; ^{joshua_8349@hotmail.com} ; Cecilia Devi Wilfred^b ; Syed Nasir Shah^a ; Matheswaran Pranesh^a ; M.I. Abdul Mutalib^a ; Kallidanthiyil Chellappan Lethesh^c ; ^{letheshkc@gmail.com}
• 关键词：Ionic liquids ; Dual functionalization ; Thermal stability ; Thermophysical property ; COSMO-RS
• 刊名：Journal of Molecular Liquids
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：225
• 期：Complete
• 页码：281-289
• 全文大小：1403 K
• 卷排序：225

文摘

New imidazolium ILs with nitrile functionality and ether group were synthesized. Thermo physical properties were measured in a wide temperature range. The dual functionalized imidazolium ILs showed thermal stability up to 300 °C. Refractive index and molar polarizability correlated by Lorentz-Lorentz equation. COSMO-RS used to predict their application in desulfurization of fuel.