Initial CaF2 reactions on Si(1 e:hsp>1 e:hsp>4)-2 e:hsp>× e:hsp>1: Isolated silicides, faceting and partial CaF adsorption
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We fabricate isolated and symmetric Ca-silicide units on Si(1 1 4)-2 × 1.

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At 0.4 ML, a (1 1 3) facet is developed through substrate etching by F.

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A 2×2 CaF overlayer is formed uniformly only on the (1 1 3) facet.

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The 2×2 CaF overlayer has no net dipole moment.

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