Convenient route to an electron-deficient Tetraosmium(I) Carboxylate chain
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- 作者：Bo Yang Chor ; Rakesh Ganguly ; Weng Kee Leong
- 关键词：Osmium ; Tetranuclear ; Carboxylate ; Chain ; Electron-deficient
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 February 2016
- 年：2016
- 卷：804
- 期：Complete
- 页码：114-117
- 全文大小：601 K
文摘
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Convenient synthesis of an electron-deficient tetraosmium chain.
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Build-up of a tetraosmium chain from a diosmium precursor.
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First example of a tetraosmium(I) carboxylate chain with an unsupported Os–Os bond.
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Computational studies of a simplified structure Os4(CO)8(μ-OOCMe)4(PMe3)2.