Micellar promoted alkenes isomerization in water mediated by a cationic half-sandwich Ru(II) complex

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• 作者：Laura Sperni ; Alessandro Scarso ; Giorgio Strukul ; ^{strukul@unive.it}
• 关键词：Allylbenzenes ; Isomerization ; Ruthenium ; Micellar media ; Surfactants
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：535-539
• 全文大小：958 K
• 卷排序：455

文摘

A Ru complex catalyzes the double bond migration in substituted allylbenzenes. High selectivity towards the E isomer is observed. The reaction is carried out in water under mild conditions with an ordinary catalyst. Surfactants are used to solubilize reactants, products and catalyst.