The first heterometallic Cu(II)/Cr(III) complex with an open-chain Schiff-base ligand self-assembled from copper powder, Reineckes salt, ethylendiamine and acetone
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- 作者：Vitalina M. Nikitina ; Oksana V. Nesterova ; Vladimir N. Kokozay ; Evgeny A. Goreshnik ; Julia Jezierska
- 关键词：Heterometallic complexes ; Reineckes anion ; Copper(II) ; Schiff-base ligand ; H-bonds
- 刊名：Polyhedron
- 出版年：2008
- 出版时间：4 August 2008
- 年：2008
- 卷：27
- 期：11
- 页码：2426-2430
- 全文大小：533 K
文摘
A novel supramolecular assembly [{Cu(enac)}2Cr(NCS)4(NH3)2][Cr(NCS)4(NH3)2]3 · 4(CH3)2CO (enac = 4,6,6-trimethyl-3,7-diazanon-3-ene-1,9-diamine), the first example of a Cu/Cr heterometallic compound containing a Schiff-base ligand such as enac, and an anion of Reineckes salt, Cr(NCS)4(NH3)2−, as a building block, was obtained by the self-assembly reaction of copper powder and Reineckes salt in an acetone/methanol (1:4) solution of ethylenediamine in the open air. An X-ray study shows that the complex includes a trinuclear Cu2Cr cation, constructed from two Cu(enac)2+ moieties and a trans-[Cr(NCS)4(NH3)2]− block as a two-linking bridging ligand. The metal–metal separations within the cation are CuCr = 6.393(31) Å and CuCu = 12.786(63) Å. The supramolecular architecture of the complex involves two types of H-bonded chains, the first chain is generated by trinuclear cations [{Cu(enac)}2Cr(NCS)4(NH3)2]2+, [Cr(NCS)4(NH3)2]− anions and (CH3)2CO molecules, while the second by crystallographically different anions of Reineckes salt and (CH3)2CO. Variable-temperature (1.8–300 K) magnetic susceptibilities show a slight change of the μB value at low temperature, indicative of weak antiferromagnetic interactions (JCuCr = −0.9 cm−1) between the paramagnetic centers.