Microstructure and orientation distribution of two phase Ni–Al(
β)/Ni
3Al(
γ′) alloys obtained by thermomechanical processing were examined using electron back-scatter diffraction pattern technique. Cylindrical specimens were hot-compressed in the
β phase region and subsequently annealed in the (
β/γ′) two phase region. After the hot deformation, equiaxed
β grains surrounded by high angle boundaries were homogeneously formed due to dynamic recrystallisation under adequate condition. Moreover, strong
111
fibre texture parallel to the compressive axis developed in the
β phase because of the lattice rotation during hot deformation. After annealing in the two phase region,
γ′ phase transformed from
β phase with
111
β fibre texture satisfying the Kurdjumov–Sachs relationship and resulting in the formation of
110
γ′ fibre texture. Film-shaped
γ′ phase preferentially often precipitated along the
β grain boundaries and a large number of (
β/γ′) boundaries were partially coherent. This thermomechanical processing was effective in controlling the crystallography of
γ′ along the
β grain boundaries.