Electrochemical properties of carbon nanocoils and hollow graphite fibers as anodes for rechargeable lithium ion batteries

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• 作者：Liyong Wang^a ; ^b ; Zhanjun Liu^a ; ^{zjliu03@sxicc.ac.cn" class="auth_mail" title="E-mail the corresponding author} ; Quangui Guo^a ; Guizhen Wang^c ; Jinhua Yang^d ; Peng Li^e ; Xianglei Wang^f ; Lang Liu^a
• 关键词：Carbon nanocoils ; Hollow graphite fibers ; Anode materials ; Lithium ion batteries ; High rate performance
• 刊名：Electrochimica Acta
• 出版年：2016
• 出版时间：1 May 2016
• 年：2016
• 卷：199
• 期：Complete
• 页码：204-209
• 全文大小：2357 K

文摘

Carbon nanocoils (CNCs) have been used as anode materials for preparation of lithium ion batteries. As pure carbon material without any chemical modification, the graphitized CNCs anode exhibited larger capacities with good Coulombic efficiency, a higher rate capability, and better reversibility than the hollow graphite fibers (HGFs) anode. The excellent performance of the CNCs was possibly ascribed to the special structure and the high degree of graphitization. As a result, the CNCs anode exhibited high reversible capacity of 385.5 mA h g⁻¹ at 50 mA g⁻¹, 104.7% reversible capacity retention after 105 cycles, and superior reversible capability of 177.4 mA h g⁻¹ at 1 A g⁻¹ after 100 cycles. This result indicated that CNCs could be an attractive choice as anode material for high-energy density and high-power lithium-ion batteries.