文摘
Bismuth-modified barium calcium zirconate titanate ceramics [(Ba1?x/2Bix)0.85Ca0.15](Ti0.90Zr0.10)O3 (BBCTZ) have been prepared by the conventional solid-state reaction method, and effects of Bi content on the electrical properties of BBCTZ ceramics were systematically investigated. BBCTZ ceramics endure a phase transition from the coexistence of rhombohedral and tetragonal phases, a tetragonal phase, to a cubic phase with increasing Bi content. The Curie temperature, the remanent polarization, and the dielectric loss of BBCTZ ceramics gradually decrease with increasing the Bi content. The BBCTZ ceramic with xxA0;= 0.0075 exhibits an optimum electrical behavior: d33 ?#xA0;361 pC/N and kp ?#xA0;40.2 % .