Design and synthesis of reactive polymers containing perfluorocyclobutyl (PFCB) and hydroxyl moieties for post-functionalization of PFCB aryl ether polymers
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- 作者：Jiangjian Hong ; Liping Bi ; Shining Li ; Guangyao Jia ; Yuanqin Zhu ; yqzhu@gxu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Guanghua Li ; Zuqiang Huang
- 关键词：Perfluorocyclobutyl (PFCB) ; Post-functionalization ; Reactive polymers
- 刊名：Polymer
- 出版年：2016
- 出版时间：14 June 2016
- 年：2016
- 卷：93
- 期：Complete
- 页码：37-43
- 全文大小：1167 K
文摘
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A new aryl trifluorovinyl ether monomer (MOTFVB) with a methoxy group was designed and synthesized.
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Perfluorocyclobutyl (PFCB)-containing reactive polymers (PFCB-OH-xx) with adjustable phenolic hydroxyl contents have been developed from MOTFVB.
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Post-functionalization of PFCB aryl ether polymers with sulfopropyl groups was accomplished using PFCB-OH-xx as precursors.
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PFCB-OX-xx could be a class of promising precursor for development of new functional PFCB aryl ether polymers.