Vibrational analysis and crystal structure of two new 1D CuII and CoII coordination polymers, involving the ligands 2,5-dihydroxyterephthalate and glutarate
详细信息 查看全文
- 作者：Leonã ; S. Floresa ; Stanley P. Alcâ ; ntaraa ; Guilherme C.G. de Limaa ; Maria I. Yoshidab ; Charlane C. Corrê ; aa ; charlane.cimini@ufjf.edu.br" class="auth_mail" title="E-mail the corresponding author
- 关键词：Vibrational absorption spectroscopy ; Raman scattering ; 2 ; 5-Dihydroxyterephthalate ; Glutarate ; Coordination polymers
- 刊名：Vibrational Spectroscopy
- 出版年：2016
- 出版时间：September 2016
- 年：2016
- 卷：86
- 期：Complete
- 页码：302-310
- 全文大小：1677 K
文摘
- •
Reactions of CuII and CoII ions with 2,5-dihydroxyterephthalic and glutaric acids were performed.
- •
The ligand bridges the metal sites giving rise to 1D coordination polymers.
- •
The presence of solvent molecules, coordinated to metal centers, leads to potentially reactive metal sites to allow Postsynthetic modifications.