Synthesis and X-ray studies of novel 3-C-nitromethyl-hexofuranoses

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• 作者：M膩ris Turks^a ; ^{maris_turks@ktf.rtu.lv" class="auth_mail} ; Krista V膿ze^a ; G募ebs Kise募ovs^b ; Jevge艈ija Mackevi膷a^a ; Jevge艈ija Lugi艈ina^a ; Anatoly Mishnev^b ; Dean Markovi膰^c
• 关键词：Henry reaction ; 3-C-Nitromethyl-gulofuranose ; 3-C-Nitromethyl-galactofuranose ; Conformations ; Altona&ndash ; Sundaralingam pseudorotation phase angle
• 刊名：Carbohydrate Research
• 出版年：4 June 2014
• 年：2014
• 卷：391
• 期：Complete
• 页码：82-88
• 全文大小：1619 K

文摘

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d="p0100">Straightforward synthesis of branched 3-C-nitrometyl-hexofuranoses is described.

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d="p0105">Novel galactofuranose and gulofuranose derivatives are characterized by X-ray diffraction analysis.

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d="p0110">Diastereoselective Henry reaction on diacetone-伪-d-gulose&mdash;derived ketone is described.

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