Isobutane alkylation with 2-butene catalyzed by amide-AlCl3-based ionic liquid analogues
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- 作者：Pengcheng Hu ; Yadong Wang ; Xianghai Meng ; Rui Zhang ; Haiyan Liu ; Chunming Xu ; Zhichang Liu ; lzch@cup.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ionic liquid analogues ; Amide structure ; Alkylation ; Isobutane ; 2-Butene
- 刊名：Fuel
- 出版年：2017
- 出版时间：1 February 2017
- 年：2017
- 卷：189
- 期：Complete
- 页码：203-209
- 全文大小：1167 K
文摘
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0.75NMA-1.0AlCl3 IL analogue was an efficient catalyst for isobutane alkylation.
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CuCl modification improved greatly both the catalytic performance and the quality of alkylate.
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C8 selectivity, TMPs/DMHs ratio and RON in semicontinuous mode reached 94.65 wt%, 14.98 and 98.40, respectively.
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C8 selectivity, TMPs/DMHs ratio and RON in batch mode reached 84.10 wt%, 14.86 and 96.54, respectively.