Oxidoperoxidotungsten(VI) and dioxidotungsten(VI) complexes catalyzed oxidative bromination of thymol in presence of H2O2-KBr-HClO4
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- 作者：Mannar R. Mauryaa ; rkmanfcy@iitr.ac.in" class="auth_mail" title="E-mail the corresponding author ; Lata Ranaa ; Fernando Avecillab
- 关键词：Tridentate ONO donor Schiff base ligands ; Oxidoperoxidotungsten(VI) complexes ; Dioxidotungsten(VI) complexes ; NMR spectroscopy ; Catalytic activity ; Oxidative bromination of thymol
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：30 January 2016
- 年：2016
- 卷：440
- 期：Complete
- 页码：172-180
- 全文大小：1771 K
文摘
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Oxidoperoxido- and dioxidotungsten(VI) complexes are reported.
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Reactivity of dioxidotungsten(VI) complexes with H2O2 has been studied.
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These complexes catalyze the oxidative bromination of thymol using 30% H2O2 at room temperature.
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These complexes act as functional models of vanadium dependent haloperoxidases.