New catalytic route: Hydrogels as templates and reactors for in situ Ni nanoparticle synthesis and usage in the reduction of 2- and 4-nitrophenols

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• 作者：Nurettin Sahiner ; Hava Ozay ; Ozgur Ozay ; Nahit Aktas
• 关键词：Hydrogel reactor ; Nanocomposites ; Ni catalyst ; Nanoparticles ; Hydrogel-template
• 刊名：Applied Catalysis A: General
• 出版年：2010
• 出版时间：15 September 2010
• 年：2010
• 卷：385
• 期：1-2
• 页码：201-207
• 全文大小：442 K

文摘

Nickel nanoparticles inside poly(2-acrylamido-2-methyl-1-propansulfonic acid) (p(AMPS)) hydrogel were prepared by reduction of Ni(II) ions absorbed within hydrogel network. TEM images confirmed that in situ formed nickel particle in p(AMPS) hydrogel networks are about 100 nm. These nickel metal nanoparticles containing hydrogel-composites were utilized as catalysts and reaction media for the reduction reactions of aromatic nitro compounds, 2- and 4-nitrophenols with aqueous NaBH₄. The reduction rate constants at four different temperatures (30, 40, 50 and 60 °C) and activation parameters were calculated. The activation energies (E_a) for 4- and 2-nitrophenols are 25.70 and 38.69 kJ mol⁻¹, respectively. It was found that these types of hydrogel-composite catalyst systems can be used repetitively up to five times with 100 % conversion and only with 25 % reduction in the initial reduction rate.