Microwave-assisted base-free oxidation of glucose on gold nanoparticle catalysts
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- 作者：Sari Rautiainena ; Petra Lehtinena ; Marko Vehkamä ; kia ; Klaus Niemelä ; b ; Marianna Kemella ; Mikko Heikkilä ; a ; Timo Repoa ; timo.repo@helsinki.fi" class="auth_mail" title="E-mail the corresponding author
- 关键词：Oxidation ; Carbohydrates ; Heterogeneous catalysis ; Gold ; Microwave chemistry
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：10 January 2016
- 年：2016
- 卷：74
- 期：Complete
- 页码：115-118
- 全文大小：309 K
文摘
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Base-free glucose oxidation with gold catalysts was promoted by microwave heating.
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76% gluconic acid in 10 min with hydrogen peroxide as oxidant
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Very high turn-over frequencies over 10,000 h− 1
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Activity of Au/Al2O3 catalyst remained unchanged during four consecutive runs