Chromocene, ferrocene, cobaltocene, and nickelocene derivatives with isopropyl and methyl or trimethylsilyl substituents
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- 作者：Heiko Bauera ; Julia Weismannb ; Dirk Saurenzc ; Christian Fä ; rbera ; Marion Schä ; rd ; Wjatscheslaw Gidte ; Ina Schä ; dliche ; Gotthelf Wolmershä ; usere ; Yu Sune ; Sjoerd Hardera ; Helmut Sitzmanne ; sitzmann@chemie.uni-kl.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：Alkylcyclopentadienyl ligand ; Ferrocene ; Cobaltocene ; Nickelocene ; Chromocene ; Crystal structure
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 May 2016
- 年：2016
- 卷：809
- 期：Complete
- 页码：63-73
- 全文大小：1435 K
文摘
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Dimethyl-diisopropylcyclopentadienyl ligands confer solubility and crystallinity.
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No other high spin chromocenes found among alkylated or silylated derivatives.
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Efficient transfer of a C5H5 ligand from nickelocene to a cationic nickel fragment.