Heterogeneous selective synthesis of 1,2-dihydro-1,3,5-triazines from alcohols and amidines via Cu/OMS-2-catalyzed multistep oxidation

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• 作者：Xu Meng^a ; Xiuru Bi^a ; Yanmin Wang^a ; Gexin Chen^a ; Baohua Chen^b ; Zhenqiang Jing^c ; Peiqing Zhao^a ; ^{zhaopq@licp.cas.cn}
• 关键词：Heterogeneous catalysis ; Multistep oxidation ; OMS-2 ; Supported catalyst ; Triazine
• 刊名：Catalysis Communications
• 出版年：2017
• 出版时间：10 January 2017
• 年：2017
• 卷：89
• 期：Complete
• 页码：34-39
• 全文大小：1006 K
• 卷排序：89

文摘

OMS-2 was synthesized via reducing KMnO4 by TBHP. OMS-2 acts as support and ETM in Cu/OMS-2 catalyst. Cu/OMS-2-catalyzed oxidative synthesis of 1,2-dihydro-1,3,5-triazines was realized. Cu/OMS-2/O2 system works through multistep oxidation.