Anisotropic behavior of layer-by-layer films using highly disordered copper hexacyanoferrate(II) nanoparticles
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- 作者：Rafael N. Soek ; Ariane Schmidt ; Herbert Winnischofer ; Marcio Vidotti ; mvidotti@ufpr.br" class="auth_mail" title="E-mail the corresponding author
- 关键词：Copper hexacyanoferrate nanoparticles ; Structural defects ; Layer-by-Layer ; Anisotropic behavior ; FTIR reflectance
- 刊名：Applied Surface Science
- 出版年：2016
- 出版时间：15 August 2016
- 年：2016
- 卷：378
- 期：Complete
- 页码：253-258
- 全文大小：1463 K
文摘
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Stable copper hexacyanoferrate nanoparticles were synthesized with no need of stabilizing agent.
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The high number of structural defects generates a strong internal dipole moment in the nanoparticle.
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The electroactivity of the PB analogue is attributed to the high number of internal vacancies.
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The nanoparticle dipole provoked an anisotropic growth on the LbL modified electrodes.